Angelina Jolie and Brad Pitt were together for over a decade.Kevin Winter / Getty For 12 years, Brad Pitt and Angelina Jolie were one of Hollywood's most iconic couples. They met around 2003 and wed in 2014 — Jolie filed for divorce in 2016. The pair reached a divorce settlement in December 2024, after eight years of legal battles. For 12 years, Angelina Jolie and Brad Pitt were one of Hollywood's most prominent couples.